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Welding skills and quality of pressure vessels made of titan

Importance of welding work
 
The pressure vessel has explosion danger, once it explodes, it will be disastrous. Facts have proved that the leakage and explosion of pressure vessels mostly come from the fracture of welded joints. Therefore, welding quality is the key to ensure the safety and reliability of pressure vessels. The state has strict requirements on the welding of pressure vessels, and the manufacturing unit must ensure the welding process qualification and welders to work with certificates before welding. In many processes of pressure vessel manufacturing (such as material, machining, forming, welding, testing, etc.), only welding can not be outsourced. It is required to adopt the welding process of our factory and be welded by our welders. All these show the importance of welding to pressure vessels. In actual production, TIG welding is the main method of welding titanium nickel pressure vessels. The welding quality awareness and operation skills of TIG welders are the key to ensure the quality of titanium nickel pressure vessels.
 
Establish welding quality awareness
 
As a TIG welder, we need to establish four kinds of welding quality awareness: clean awareness; Protection awareness; Penetration awareness; Full and beautiful consciousness.
 
2.1 pre welding treatment
 
Cleanliness has a great impact on the welding quality of titanium nickel materials. Impurities such as moisture, grease, rust and oxide film will appear defects such as pores, inclusions and cracks when melted into the weld metal. Special attention shall be paid to the fact that sulfur and lead containing substances shall not remain on the surface. When TIG welding titanium, pores are more likely to appear, because its welding wire contains deoxidizers such as Mn, Ti and Al, unlike nickel welding wire.
 
2.1.1 before welding nickel materials, stainless steel wire brush or metal milling head can be used to remove the oxide film on the groove and its surface with a width of 20mm on both sides, and acetone or alcohol can be used to remove grease, dust and other pollutants. The oxide layer generated by thermal cutting on the surface of nickel groove shall be polished and removed, and see metal luster. The melting point of the oxide film of nickel is much higher than that of the base metal (for example, the melting point of the oxide film of nickel is 2090 ℃, and the melting point of pure nickel is 1450 ℃, with a difference of about 640 ℃). If the oxide film is not melted during welding, it will lead to slag inclusion in the weld metal. Therefore, this oxide film must be removed before welding.
 
2.1.2 titanium and titanium alloy welding wires, groove surfaces and the range of 20mm on both sides shall be cleaned. Degreasing or mechanical cleaning can be selected according to the degree of surface pollution. The cleaned welding wires and weldments shall not be touched directly by hand. For the groove processed by flame methods such as gas cutting and plasma cutting, 2 ~ 3mm shall be machined from the discolored part. The processed groove surface shall be flat and smooth without crack, delamination, inclusion, burr, flash and oxidation color. The groove surface shall be silvery white metallic luster. In particular, it should be noted that the oxide film must be removed within 10mm on both sides of the groove of the titanium plate on the sandblasted surface, and welding can be carried out after seeing the metallic luster. Otherwise, there will be pores at the edge of the weld.
 
2.1.3 before the heat exchanger passes through the pipe, the surface attachments of the whole pipe of the heat exchange pipe shall be removed; Remove the oxide film, oil stain, water stain and burr on the surface of the pipe end; The cleaning length shall not be less than the outer diameter of the pipe and shall not be less than 25mm. Oil stain and burr shall be removed from the tubesheet and baffle as a whole. When the extension of the heat exchange tube from the tube sheet is too long, it shall be flattened by mechanical method, and grinding wheel shall not be used.
 
2.1.4 polish and remove the residual titanium within 10mm of the groove edge of titanium steel composite plate. This residual titanium will form microcracks when melted into the steel weld.
 
2.1.5 residual high alloy at the edge of stepped groove of nickel steel composite plate must be polished and removed. This kind of high alloy will produce brittle hard phase or crack in the weld of steel.
 
2.1.6 before cladding welding of composite plates (including titanium steel and nickel steel), the interior of the whole cylinder shall be cleaned without dust, iron chipping and other dirt. The surface within 25mm on both sides of the cladding groove and the surface of the titanium cover plate shall be polished and scrubbed with acetone before welding.
 
2.1.7 the welding wire shall be cleaned with acetone before use.
 
Pre welding treatment is to pay attention to cleanliness: the plant is clean; The weldment is clean; Clean welding wire; People are clean. The professional titanium nickel container manufacturer shall have a clean workshop, and the operators shall wear clean work clothes and clean leather gloves.
 
2.2 argon protection
 
The surface of base metal and welding material must be clean to prevent pollutants from melting into the weld; High temperature molten pool and high temperature weld bead must be effectively protected by inert gas to prevent oxidation of weld metal, which are important conditions for obtaining high-quality welded joints. Therefore, argon protection is the most basic requirement for welding titanium nickel materials. Oxidation will weaken the mechanical properties and corrosion resistance of welded joints.
 
The welding of titanium and nickel materials shall have protection awareness and master protection technology. The higher the activity of the metal, the stricter the requirements for protection. 99.99% pure argon is required for titanium, 99.999% high-purity argon is required for zirconium, and tantalum shall be welded in a closed argon filled gas chamber.
 
Making appropriate protective tooling (usually called protective box) according to the actual shape of the welded joint is not only the skill that tungsten argon arc welder should have, but also an important preparation for welding titanium nickel materials. Therefore, the welder has two tasks: one is to weld well and the other is to protect well. Welding and protection complement each other. It's useless if welding is well protected, and it's useless if welding is well protected. Welding is prohibited without proper protective measures.
 
There are two ways of protection: trailing cover protection and argon filling protection. Trailing cover protection can be used without argon filling protection. The space filled with argon is often large, which not only has poor protection effect, but also consumes gas.
 
2.2.1 as long as tungsten argon arc welding is adopted, argon protection must be provided for high-temperature (titanium material is above 400 ℃) weld pool or weld bead, even ordinary carbon steel. When argon arc backing is used for the first layer welding of carbon steel and stainless steel, the back shall also be protected by argon. Carbon steel is silver white after being well protected. There is no problem with radiographic testing of unprotected joints, but the performance (especially back bending) is not necessarily qualified.
 
2.2.2 when spot welding and positioning the workpiece with TIG welding group, the back can be protected with a trailing cover if it can be protected with a trailing cover. For small diameter, the interface can be filled with argon for protection.
 
2.2.3 there are two forms of welding between heat exchange tube and tubesheet of heat exchanger, one is pipe head melting (broken head welding) and the other is pipe head non melting (reserved head welding). Copper plug (as shown in Fig. 1) is added for broken head welding to prevent and reduce argon loss from the welding handle nozzle during welding. Protective tooling (as shown in Fig. 2) shall be added in the pipe for reserved head welding and protected by argon.



The extension length of the pipe with reserved head welding shall be 4mm or more, so that the pipe head will not be bitten during welding. If necessary, the pipe head can be mechanically cut to the length meeting the drawing requirements after welding. In addition to ensuring root fusion, special attention shall be paid to the non oxidation and non melting of the inner wall of the pipe.
 
2.2.4 it is extremely wrong to weld a layer of well protected weld bead on the oxidized weld bead, especially for the titanium head or cylinder longitudinal seam formed after splicing.
 
2.2.5 after welding, the surface of titanium material shall be silver white or light yellow without blue. It is wrong to remove the blue by a second pass of welding or by welding a torch. The correct method is to brush or grind off the oxidized deposited metal.
 
2.2.6 for titanium steel clad plate equipment, the leak detection hole plays three roles: when welding titanium cover plate, argon is introduced into the leak detection hole to protect the back; Air tight leak detection after welding; Leakage signal hole in operation.

When welding the titanium steel clad plate cylinder, the leak detection hole (welding leak detection nozzle) and gas path blocking (silver brazing) shall be designed as shown in Figure 3, that is, two leak detection holes on the longitudinal seam and two leak detection holes on the circumferential seam (as shown in Figure 4); After the gas path is blocked, the longitudinal weld and circumferential weld are not connected. During the welding of the first layer, stickers shall be pasted on both sides of the front of the titanium cover plate to be welded and removed while welding (as shown in Figure 5). The length of uncovering paper on one side shall not exceed 250mm, and the length of one-time welding shall not exceed 200mm. It shall be carried out alternately on both sides. During the welding of the second layer, the leakage detection hole shall continue to be protected by argon. When argon is passed through the leak detection hole, part of argon flows to the welding area and the other part flows out of another leak detection hole.

Photo 5 sticker welding of titanium cover plate at nozzle of titanium steel composite plate
 
2.2.7 due to the majority of titanium vessel thin plates, when welding accessories on the cylinder or head, the corresponding other side shall not be oxidized.
 
In the actual manual welding operation, one welder needs one or two protectors for welding. The protector should pay attention and move the protective trailing cover closely with the movement of the welding handle, which is called heel box protection (as shown in Fig. 6 and Fig. 7). The protector of the front heel box shall not follow too tightly and collide with the welding handle, which will affect the welder's operation, or follow too slowly, and the protection effect will become worse. The protector of the back heel box shall move the protective cover from time to time according to the movement of the bright spot in the welding pool. Therefore, the acquisition of a high-quality weld is the result of the cooperation between welders and protectors, and the protectors are credited.

Due to the diversity and complexity of weldment structure, it is not easy to do a good job of protection, which should be paid enough attention. Protective tooling shall be prepared and verified before welding. The welding protection of nickel expansion joint, titanium head, elbow, tee and titanium steel composite plate should be solved.
 
2.3 penetration
 
Incomplete penetration is equal to weakening the pressure bearing thickness. Like cracks, it is an impermissible welding defect, which involves the safety of pressure vessels.
 
Class A and B butt joints of pressure vessels can be fully welded in most cases because they need to undergo radiographic testing. Incomplete penetration often occurs in the class D fillet joint between nozzle and cylinder, especially with reinforcing ring. Because such welded joints often have no requirements for radiographic or ultrasonic testing, operators have not developed the awareness of penetration for a long time. If no special prompt is given, there are many cases of incomplete welding of nozzle.
 
Penetration requires groove processing in place, which is convenient for penetration and can not have a large assembly gap. If possible, the groove can be machined. If not, plasma or flame cutting can be used, but the grinding allowance shall be reserved.
 
The detection method is an important means to cultivate the welder's awareness of penetration.
 
2.4 full and beautiful welds
 
The so-called weld fullness means that the weld filler metal of the butt joint is not lower than the surface of the base metal, and the weld leg height of the fillet joint meets the drawing requirements. Whether the weld is full is related to the number of welding layers. If it is not full, the number of welding layers is not enough. Plumpness of weld and height of weld leg are the easiest problems to solve, but they are often ignored. Uniform weld formation and uniform welding wave are beautiful.
 
The highest level of welding operation is to pursue the external beauty of the weld while ensuring the internal quality of the weld. Gorgeous inside and outside is the ultimate goal of welding quality. If the weld appearance is qualified, it may not be beautiful. What are the criteria for evaluating beauty? There is only one way here, that is, looking at "comfort" is like appreciating a handicraft.
 
Do not take the weld repair as the reason for the unsightness of the weld. It must be clear that the weld repair is the most serious damage to the weld surface quality, and try to avoid the weld repair.
 
Therefore, we should establish the welding concept of "welding well, seeking better and welding well at one time".
 
"Good welding" is the most basic requirement to ensure that the comprehensive performance of the welded joint is qualified;
 
"Seeking better" is the beauty of weld bead;
 
"One-time welding" means no repair, no damage to the appearance quality of the weld, and no waste of time and materials.
 
Deeply understand the connotation of welding quality
 
The welding quality shall ensure the mechanical properties or corrosion resistance of the welded joint, which is not only qualified in NDT, but also able to withstand the double inspection of "flaw detection" and "performance" like the test piece of welder examination. NDT qualification cannot be regarded as the only qualification index, otherwise, it is a superficial understanding. Qualified NDT is far from qualified quality. It is a necessary condition for qualified quality, not a sufficient condition. There are many indicators of qualified quality, and there are different requirements for different materials or service environment.
 
Qualified welding shall at least include the following 5 items:
 
1) NDT qualified;
 
2) Mechanical properties are qualified;
 
3) Acceptable color (titanium weld bead interlayer and final surface);
 
4) Qualified corrosion test (stainless steel or corrosion resistant alloy);
 
5) The metallographic structure is qualified (duplex stainless steel).
 
Enhance the sense of responsibility
 
Working according to drawings, standards and processes is called a sense of responsibility. Product quality is dry, not drawn or made up. Therefore, both at home and abroad attach great importance to the actual welding operation, and it is mandatory for welders to work with certificates.
 
No matter how well the welding process is compiled, it can only be reflected in the product through the operation of the welder. Welding quality is in the hands (operation skills) and hearts (sense of responsibility) of each welder. Not only by hand, but also by heart. Poor operation skills can be gradually improved. It's not terrible. What's terrible is that you don't have a sense of responsibility and don't work according to the process. The welding method, welding material and welding parameters formulated according to the welding process are the bottom line of the welder. Conscientious and meticulous implementation of the process is the welder's professional ethics. Honesty is the foundation of life and career, and fraud is equal to harming yourself. If you don't work according to the craft, you are making a fake or a bomb. Poor quality will harm the interests of the enterprise, the country and the people, and eventually harm themselves, the enterprise and the society.
 
The "20% inspection" shall be correctly understood, and the welder shall be responsible for the quality of the whole weld. The regulations clearly stipulate that the manufacturer shall also be responsible for the quality of the undetected part of the pressure vessel undergoing local nondestructive testing. "20% inspection" should not only pay attention to the so-called "T-shaped mouth", not to mention that 20% should be welded and the remaining 80% can be dealt with, but 100% should be welded and 100% should be the responsibility of the welder. It should be said that the detection proportion has nothing to do with the welder. The welder should not care too much about the detection proportion. If he cares too much, he has ideological problems. This idea is dangerous. In addition, due to the existence of "20% inspection", the welder should not place all the welding quality on the inspection, or become an excuse. The welder should also be responsible for the welding quality of the undetected part.
 
The welder is responsible for the welding quality. Everyone should also create good welding conditions for the welder. If the conditions are not met, the welder can refuse to weld. The welder has the right to refuse welding if the groove processing is not in place, the assembly is unqualified, the cleaning is not clean before welding, there is no protection or the protection cannot achieve the effect.
 
Improve operation skills
 
The skills of apprentices who have received short operation training can not meet the requirements of work, so they should make more use of their spare time to practice their operation skills. Only after having basic operation skills can they take the post, which is the beginning of substantial improvement of skills. Welder skills are not practiced on the test board, but on the product. The more work you do, the faster your skill level will improve. When you can weld type A / b joints of cylinder and pipe heads of heat exchanger, you are a mature welder.
 
An excellent TIG welder needs two skills: operation and making protective tooling.
 
During TIG welding, the operation method of short arc without swinging, straight line or micro swinging shall be adopted to keep the center line of tungsten electrode at 80 ° ~ 85 ° with the workpiece surface, and the included angle between filler wire and workpiece surface shall be as small as possible, generally about 10 °. The feeding of filler wire is not directly immersed in the molten pool, but to make the filler wire in front of the tungsten electrode melt and feed at the same time, that is, the so-called twist wire and spot wire, which can prevent non fusion and beautiful welding wave. The faster the spot wire speed is, the finer and more uniform the welding wave will be and the more beautiful the weld bead will be. The rhythmic "pop" sound of molten droplets melting into the molten pool is the most beautiful note of TIG welding.
 
The first layer of weld bead at the root of nickel material may have post weld cracking, i.e. thermal crack. At this time, the method of adding more filler wires to increase the thickness of deposited metal can be used to remedy it. The arc crater shall be filled during arc stopping to prevent arc stopping cracks.
 
The so-called "rocker welding" is not suitable for the welding of titanium nickel materials. The swing amplitude of this operation method is large, and the argon protection effect becomes worse; Slow walking speed, wide weld bead and large linear energy; Incomplete fusion may occur when the wire is continued rather than dotted.
 
Titanium material can swing properly on the premise of good protection of molten pool, so as to ensure good fusion with base metals on both sides and weld bead forming quality. In order to ensure the corrosion resistance of the joint, nickel materials advocate multi-pass welding, do not swing as much as possible, and press one weld at a time, commonly known as "braided welding". When the welding speed comes up, the heat input is naturally small, which is beneficial to prevent overheating and improve the comprehensive performance of the welded joint. When you see that the weld surface is thin pass and multi pass welding, you can conclude that this is the work of a knowledgeable welder.
 
The hot end of the welding wire shall always be under the argon protection of the welding handle, that is, when the arc is stopped, the end of the welding wire shall not leave the protection area of the welding handle immediately, but shall stay for 3 ~ 4 seconds, so that the welding wire head must be silver white. However, most welders do not form the habit of pausing for a moment. As soon as they stop the arc, they can't wait to open the welding cap to see what's going on. It's a little short of an excellent TIG welder. It is difficult to cut off the end of the oxidized welding wire before each re welding.
 
While training welders' operation skills, they should also cultivate welders' protection awareness and learn how to protect, that is, learn to make protective tooling. Because no matter how well formed the weld bead is oxidized, it is futile.
 
In addition to operating skills, welders should also master some "should know and should know". When welders pick up welding materials for welding, they should know what materials are welded and what welding materials are used, understand the weldability of materials, and be able to judge the correctness of the use of welding materials. Using wrong welding materials is a serious quality accident. We won't agree with such welders. They do a good job, but they don't know what welding materials they use and what materials they weld.
 
Process control
 
Process control is the essence of welding quality control. If the process is good, the result will be good. Process control includes the use of welding materials, drying of welding rods, groove processing, cleaning of welding wires and weldments, preheating before welding, welding parameters, interlayer temperature, number of welding layers, surface color of weld bead, etc.
 
Welding current is the most important parameter of welding specification. Controlling welding current is to control heat input. The heat input has an effect on the mechanical properties and corrosion properties of the joint. In order to obtain balanced austenite and ferrite duplex structure, duplex stainless steel needs to choose moderate welding heat input. In addition, all materials shall adopt small welding heat input, especially austenitic stainless steel and titanium nickel materials.
 
The interpass temperature has been renamed "interpass temperature", which is a reasonable name. It is clear that the interpass temperature should also be controlled for surfacing, not the interpass temperature. The purpose of controlling the temperature between channels is the same as that of controlling the welding current, which is to prevent overheating. For steel grades requiring preheating before welding, the interpass temperature shall not be lower than the preheating temperature. In addition, the lower the inter channel temperature, the better (but not lower than 15 ℃). Considering the welding efficiency, the interpass temperature of carbon steel and low alloy steel shall not exceed 300 ℃, that of austenitic stainless steel and nickel materials shall not exceed 150 ℃, and that of titanium materials shall not exceed 120 ℃.
 
The number of welding layers is also the key to ensure no leakage after welding. It shall be clearly stated that pressure bearing welds are not completed by welding only one layer, and two or more layers shall be welded. At least two layers of welds shall be welded between heat exchange tube and tube sheet, titanium cover plate of titanium steel composite plate, welding ring and liner pipe, flange and connecting pipe.
 
The color inspection of titanium welding bead surface is the most important link to be controlled. The emphasis here is on the weld bead surface color, not the final post weld surface color, that is, the weld bead color of each layer shall be checked. There is no problem that the oxidized welded joint reaches grade I radiographic inspection, and NDT can not solve the oxidation problem.
 
There are non traceable aspects in the welding process, such as welding current, number of welding layers, surface color between passes, etc. once the welding is over, there is no way to find it. Therefore, welding process control is very important.
 


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